Section 5: Logarithms

Logarithms are often used in chemistry.  For example, we use a logarithms to show how strong an acid is on the pH scale. A logarithm is a just function that answers a simple question: To what power must the base of the logarithm be raised to get the given number? 

pH is a logarithmic scale (https://www.flickr.com/photos/lwr/5062032214, CC BY-SA 2.0 )

For example,

Log327 = 3                           since 33 (3 x 3 x 3) is 27.

In other words, Log327 = 3 means “the base of 3 raised to what power equals 27”.

Log28 = 3                             since 23 (2 x 2 x 2) is 8.

In other words, Log28 = 3 means “the base of 2 raised to what power equals 8”.

If no base is given, the logarithm is assumed to have a base of 10.

Log 100 = 2                         since 102 is 100.

Log 1000 = 3                       since 103 is 1000.

While these examples are fairly straightforward, could you easily find the log of a number like 437?

Log 437 = ?

Ten raised to what power is 437?  I don’t know! Do you?

In the past, the last several pages of any upper level math book would have tables of logarithms.  Students like you would have to look up the answer to a logarithm in the back of their book.

No calculator, no problem!(Internet Archive Book Images, No restrictions, via Wikimedia Commons)

Alternatively, they might have used a device like this one, called a slide rule.   

A Vintage Slide Rule (Joe Haupt from USA, CC BY-SA 2.0 , via Wikimedia Commons)

Thankfully, you can just use your calculator, or your phone, or practically any online calculator you can find.  .

A modern slide-rule (Peter Frank, Österreich, CC BY-SA 3.0 , via Wikimedia Commons)

Use your calculator to find the base 10 log of 437. Make sure you get the same answer below!

Log 437 = 2.64

Meaning, 102.64 = 437.

A natural logarithm (given the symbol, ln), uses the base, e.

e is called Euler’s number and is approximately equal to 2.71828.   e is called a transcendental number, like pi.  Find the ln button on your calculator and perform the calculation below.

ln 100 = 4.6

Meaning, e4.6 = 100

In other words, 2.718284.6 = 100

What is the point of using logarithms in chemistry? There are actually two reasons. First, sometimes logarithms are better at making predictions, like how long it will take for a certain amount of product to form in a given chemical reaction. Second, they are useful in converting big differences in numbers into small difference. The pH scale is a great example. A difference of 2 units in pH actually corresponds to a hundred times difference in acid strength.